Posted by Admin on March, 23, 2021
Thiocarbonyldiimidazole is based on two imidazole rings. It is simple to displace the imidazole groups on TCDI to work it in a safer option to thiophosgene.
Thiocarbonyldiimidazole (TCDI) is thiourea having two imidazole rings. It is referred to the sulfur analog of the peptide combination reagent carbonyldiimidazole. It is used is normally used as a reagent to perform out the deoxygenation of vicinal diols by making cyclic thionocarbonate in the Corey-Winter alkene mixture. It is helpful as a reagent in the enantioselective total mixture of 12-epi-fischerindole U, hapalindole Q, and welwitindolinone A.
Some important uses and features of this chemical are-
-It is helpful in the making of the xanthates, trithiocarbonates, and dithiocarbamates as agents of the chain for the reversible addition breakup chain transfer and macromolecular design polymerization.
-It is easy to displace the imidazole groups on TCDI let to work in a safer choice to thiophosgene. The behavior has been utilized in the Corey–Winter olefin synthesis. Possibly, it might change carbonothioyl species in the Barton–McCombie deoxygenation. More uses comprise the mixture of thiocarbamates and thioamides. Similar to the analogous CDI, it might be used for the peptide coupling.
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